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NOTAS SOBRE EL PRINCIPIO DEL AUMENTO DE LA ENTROPIA. ALCANCE DE UNA HIPOTESIS DE DOS FACTORES

AUGUST 1930   -  Volume: 5 -  Pages: 393-397

DOI:

[No data]

Authors:

JOSE RICARDO DE ZUBIRIA

Disciplines:

  • Physical chemistry (TERMODINAMICA )

Downloads:   176

How to cite this paper:  
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Received Date :   1 August 1930


Key words:
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Article type:
ARTICULO DE INVESTIGACION / RESEARCH ARTICLE
Section:
VARIOUS

En artículos anteriores ha enunciado el que esto escribe, una hipótesis de dos factores, oponiéndola a la hipótesis de Clausius de un solo factor. El segundo principio de la termodinámica es una hipótesis; no lo demuestra la experiencia, ni se demuestra partiendo de postulados que tengan el carácter de axiomas. En el caso ideal de Carnot, es una ley para un caso límite—una abstracción — dentro de un concepto completamente gratuito de máquina ideal. En el concepto de Clausius, es una hipótesis de un factor de degradación. A esa hipótesis de un solo factor, hemos opuesto una hipótesis de dos factores; hipótesis que creemos debe poder dejar de serlo, pues nos parece que debe poderse demostrar experimentalmente la existencia de un factor de sobregradación simultáneo con el de degradación.

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